We present 2 mu m (K band) spectra of 180 well-studied, optically visi
ble, luminous stars. Most of the stars are of OB spectral type, but we
have also included a number of Oe and Be stars, OBN and OBC stars, co
ol hypergiant stars, and high-mass X-ray binary stars. Our aim in stud
ying normal OB stars is to develop an empirical relationship between 2
mu m spectral features of these massive stars and their stellar tempe
rature and luminosity. We find the system of lines between 2.0 and 2.2
mu m is particularly good for differentiating the early- and mid-O ty
pe stars. In the late-O and early-B stars, differentiation becomes mor
e difficult, as the features show only moderate changes. We have devel
oped a spectral classification system for the K band to be used to est
imate effective temperatures of O and early-B stars. We demonstrate th
at K-band spectroscopy is superior in estimating the temperature of ho
t, luminous stars than the traditional methods of using infrared or ev
en optical photometric colors alone. The only requirements are that ad
equate resolution (R > 1000) and signal-to-noise (S/N similar to 70) b
e achieved. With our classification system, stars behind large amounts
of visible extinction, such as in young, heavily reddened H II region
s throughout our Galaxy, may be identified and studied for the first t
ime through 2 mu m spectroscopy. Emission lines are commonly seen in t
he K-band spectra of supergiant stars, however, the OBN supergiants, w
hich have a higher ratio of some processed materials at their surface,
may be more likely to show line emission, especially the He I singlet
transition at 2.058 mu m. This has led us to propose an evolutionary
scenario for some of the Galactic center He I emission-line stars, whi
ch evokes rotational mixing (Maeder 1987; Langer 1992) to explain both
the strong line emission and high luminosity of these mysterious sour
ces. We have compared our spectroscopic database with the most recent
stellar atmosphere models. We are encouraged by the good match between
the model line profiles at 2 mu m of Schaerer et al. (1996b) and thos
e observed in OB stars. Finally, we include a thorough discussion of t
he observational and reduction methods employed to obtain the spectra
shown in this atlas for the benefit of those wishing to obtain similar
, classification-quality, near-infrared spectra.