CHLOROPHYLLS .8. SYNTHESIS OF A NEW CHLOROPHYLL DERIVATIVE AND ANTHRAQUINONE-BASED DYAD AND TRIAD MOLECULES FOR EXECUTING PHOTOINDUCED ELECTRON-TRANSFER

Authors
TAUBER AY HELAJA J KILPELAINEN I HYNNINEN PH
Citation
Ay. Tauber et al., CHLOROPHYLLS .8. SYNTHESIS OF A NEW CHLOROPHYLL DERIVATIVE AND ANTHRAQUINONE-BASED DYAD AND TRIAD MOLECULES FOR EXECUTING PHOTOINDUCED ELECTRON-TRANSFER, Acta chemica Scandinavica, 51(1), 1997, pp. 88-93
Citations number
21
Categorie Soggetti
Chemistry,Biology
Journal title
Acta chemica Scandinavica → ACNP
ISSN journal
0904213X
Volume
51
Issue
1
Year of publication
1997
Pages
88 - 93
Database
ISI
SICI code
0904-213X(1997)51:1<88:C.SOAN>2.0.ZU;2-#
Abstract
A new chlorophyll derivative and anthraquinone based dyad and triad mo del compounds have been synthesized. Trifluoroacetic anhydride is show n to be an efficient reagent for ether bond formation between 3(1)-hyd roxyphytochlorin and 2-(hydroxymethyl)anthraquinone. The application o f Mukaiyama's reagent for the final esterification allowed us to creat e quite complex molecules under very mild conditions. All diastereomer s of the new dyads and triads were successfully separated using HPLC t echniques.