The uniformity and reaction kinetics of ion-beam deposited Al/Ni multi
layer samples with the same composition, Al81.8Ni18.2, and modulation
wavelength, Lambda = 20 nm, but with different total film thicknesses
were investigated by x-ray diffraction and differential scanning calor
imetry measurements. The total film thicknesses varied between approxi
mately 0.5 and 2.0 mu m It was found that the interface widths were ap
proximately 1 nm and the Ni layers are much more disordered than the A
l layers. The thicker samples show an increase in disorder on a length
scale comparable to Lambda. In other experiments, a change was observ
ed with increasing modulation wavelength from semicoherent interfaces
with a low density of misfit dislocations to semicoherent interfaces w
ith a high density of misfit dislocations. The reaction kinetics for f
orming the Al9Ni2 phase is independent of the sample thickness.