ENETHIOL ASSISTED [3,4]-SIGMATROPIC AND [3,5]-SIGMATROPIC REARRANGEMENTS DURING THIONATION OF 2,3-DIAROYLBICYCLO[2.2.1]HEPTA-5-ENES WITH BORON SULFIDE

Authors
KIM DSHL FREEMAN F
Citation
Dshl. Kim et F. Freeman, ENETHIOL ASSISTED [3,4]-SIGMATROPIC AND [3,5]-SIGMATROPIC REARRANGEMENTS DURING THIONATION OF 2,3-DIAROYLBICYCLO[2.2.1]HEPTA-5-ENES WITH BORON SULFIDE, Tetrahedron letters, 38(5), 1997, pp. 799-802
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
5
Year of publication
1997
Pages
799 - 802
Database
ISI
SICI code
0040-4039(1997)38:5<799:EA[A[R>2.0.ZU;2-C
Abstract
Thionation reaction of 2,3-diaroylbicyclo[2.2.1]hepta-5-enes using in situ generated B2S3 (bis-trialkyltin sulfide or bis-trimethylsilyl sul fide reacted with BCl3 in toluene) gave [3,4] and [3,5] sigmatropic re arrangement products. (C) 1997, Elsevier Science Ltd.