Yh. Hu et al., EFFECTS OF SURFACE MIGRATION OF ADSORBED SPECIES ON DESORPTION, Science in China. Series B, Chemistry, life sciences & earth sciences, 38(8), 1995, pp. 903-911
The TPD equation with surface migration of adsorbed species on two kin
ds of adsorbing sites being put into consideration was derived. Accord
ing to the equation, a series of theoretical TPD curves were simulated
by computer. From the results, one can see that surface migration of
adsorbed species affects greatly the shape and position of the TPD pea
ks as well as the resolution power of TPD spectra.