DYNAMIC CORRELATIONS IN A DENSE DIPOLAR LIQUID

Citation
J. Dawidowski et al., DYNAMIC CORRELATIONS IN A DENSE DIPOLAR LIQUID, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 52(3), 1995, pp. 2787-2796
Citations number
33
Categorie Soggetti
Physycs, Mathematical","Phsycs, Fluid & Plasmas
ISSN journal
1063651X
Volume
52
Issue
3
Year of publication
1995
Part
A
Pages
2787 - 2796
Database
ISI
SICI code
1063-651X(1995)52:3<2787:DCIADD>2.0.ZU;2-V
Abstract
The microscopic dynamics of liquid sulphur dioxide is investigated by means of the concurrent use of inelastic neutron scattering and molecu lar dynamics simulations. This enables an approximate separation of th e dynamic processes contributing to the neutron spectra, thus allowing us to quantify the deviation from idealized behavior of quantities ch aracterizing the single-particle and collective motions. From a compar ison between experiment and simulation, an estimate of an inelastic st ructure factor comprising information about the extent of orientationa l correlations is derived. Finally, the relevance of the present resul ts as benchmarks to assess recent predictions is discussed.