J. Dawidowski et al., DYNAMIC CORRELATIONS IN A DENSE DIPOLAR LIQUID, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 52(3), 1995, pp. 2787-2796
The microscopic dynamics of liquid sulphur dioxide is investigated by
means of the concurrent use of inelastic neutron scattering and molecu
lar dynamics simulations. This enables an approximate separation of th
e dynamic processes contributing to the neutron spectra, thus allowing
us to quantify the deviation from idealized behavior of quantities ch
aracterizing the single-particle and collective motions. From a compar
ison between experiment and simulation, an estimate of an inelastic st
ructure factor comprising information about the extent of orientationa
l correlations is derived. Finally, the relevance of the present resul
ts as benchmarks to assess recent predictions is discussed.