A NEW METHOD FOR ANALYZING DIFFERENTIAL CAPACITANCE EQUILIBRIUM CURVES AT THE ADSORPTION OF SIMPLE ORGANIC-SUBSTANCES ON ELECTRODES

Authors
DAMASKIN BB SAFONOV VA BATURINA OA
Citation
Bb. Damaskin et al., A NEW METHOD FOR ANALYZING DIFFERENTIAL CAPACITANCE EQUILIBRIUM CURVES AT THE ADSORPTION OF SIMPLE ORGANIC-SUBSTANCES ON ELECTRODES, Russian journal of electrochemistry, 31(8), 1995, pp. 788-795
Citations number
19
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
31
Issue
8
Year of publication
1995
Pages
788 - 795
Database
ISI
SICI code
1023-1935(1995)31:8<788:ANMFAD>2.0.ZU;2-J
Abstract
A new version of the statistical method for determining the adsorption parameters that is based on the optimization of differential capacita nce curves in solutions of simple organic substances is developed. The method is used for analyzing data earlier published concerning the ad sorption of ethyl, n-propyl, and n-butyl alcohols on a mercury electro de from aqueous solutions with 0.1 M NaF as the supporting electrolyte . The applicability to these systems of certain phenomenological model s for the reversible adsorption of organic substances on electrodes is discussed.