ELECTRICAL DOUBLE-LAYER STUDIES IN THE NACLO4 ETHYLENE-GLYCOL SYSTEM

Authors
JURKIEWICZHERBICH M MUSZALSKA A JASTRZEBSKA J
Citation
M. Jurkiewiczherbich et al., ELECTRICAL DOUBLE-LAYER STUDIES IN THE NACLO4 ETHYLENE-GLYCOL SYSTEM, Russian journal of electrochemistry, 31(8), 1995, pp. 846-849
Citations number
15
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
31
Issue
8
Year of publication
1995
Pages
846 - 849
Database
ISI
SICI code
1023-1935(1995)31:8<846:EDSITN>2.0.ZU;2-V
Abstract
The specific adsorption of perchlorate ions on a mercury electrode fro m ethylene glycol solutions was studied by capacity measurements of th e double layer and interfacial tension as a function of the NaClO4 con centration. The amounts adsorbed were calculated, and the capacity was resolved into its component parts with the aid of diffuse-layer theor y. The results were analysed using the Frumkin isotherm to characteriz e specific adsorption of the ClO4- ions. The electrostatic properties of the inner layer also were determined and discussed.