Reactive Powder Concretes (RPC) are characterized by high silica fume
content and very low water to cement ratio. Granulometry and heat trea
tment were optimized to obtain excellent mechanical and durability pro
perties. The study of several RPC compositions by Mercury Porosimetry,
Thermogravimetric Analysis and X-ray diffraction made it possible to
better understand their microstructural properties depending on their
heat treatment. Influence of temperature on hydration and pozzolanic r
eaction were examined. For high temperature, the presence of a crystal
hydrate, xonotlite, was observed. Mercury Porosimetry also showed tha
t a minimum porosity could be obtained with selected heat treatment.