DIFFUSION HINDRANCE VS WOOD-INDUCED CATALYTIC ACTIVATION OF MUF ADHESIVE POLYCONDENSATION

The reaction of hardening of melamine-urea-formaldehyde (MUF) adhesive resins in the presence of wood and cellulose was confirmed to have a lower energy of activation than the MUF adhesive alone, both in the pr esence or absence of ammonium chloride hardener, thus both in mildly a cid and mildly alkaline environments. DSC exotherms showed that during hardening of melamine to melamine, melamine to urea, and urea to urea crosslinks through methylene bridges occur. Only the earliest reactio n, mainly melamine to melamine crosslinking, presents a decrease in en ergy of activation which can be assigned to catalytic activation by th e cellulosic substrate. The other types of crosslinking reactions (i) appear not to occur due to the more favorable and rapid melamine to me lamine reaction which precedes them at lower temperature or (ii) do no t present catalytic activation by the substrate but rather hindrance b y it or (iii) variation of their energy of activation appears to be du e to increased diffusion hindrance by the substrate caused by the incr easing molecular weight of the resin while hardening. This because the Kissinger equation plots of the resin alone are in the main linear, f or all the exotherms, indicating that in hardening of the resin alone diffusion problems appear to be limited. (C) 1995 John Wiley & Sons, I nc.