PHOTOCYCLIZATION-FRAGMENTATION ROUTE TO LINEAR TRIQUINANES - STEREOCONTROLLED SYNTHESIS OF (+ -)-ENDO-HIRSUTENE/

Authors
RAWAL VH FABRE A IWASA S
Citation
Vh. Rawal et al., PHOTOCYCLIZATION-FRAGMENTATION ROUTE TO LINEAR TRIQUINANES - STEREOCONTROLLED SYNTHESIS OF (+ -)-ENDO-HIRSUTENE/, Tetrahedron letters, 36(38), 1995, pp. 6851-6854
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
38
Year of publication
1995
Pages
6851 - 6854
Database
ISI
SICI code
0040-4039(1995)36:38<6851:PRTLT->2.0.ZU;2-2
Abstract
An efficient, stereocontrolled synthesis of (+/-)-endo-hirsutene was a ccomplished, wherein the key steps include intramolecular Diels-Alder and Paterno-Buchi reactions to build complexity, and a reductive fragm entation to unravel the hidden linear triquinane skeleton.