HYDROBORATION OF METHYL 2-ACETAMIDOACRYLATE .2. NEW ASPECTS OF THE REACTIVITY OF THE RESULTING OXYTRIORGANOBORATES

Authors
DENNIEL V BAUCHAT P CARBONI B DANION D DANIONBOUGOT R
Citation
V. Denniel et al., HYDROBORATION OF METHYL 2-ACETAMIDOACRYLATE .2. NEW ASPECTS OF THE REACTIVITY OF THE RESULTING OXYTRIORGANOBORATES, Tetrahedron letters, 36(38), 1995, pp. 6875-6878
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
38
Year of publication
1995
Pages
6875 - 6878
Database
ISI
SICI code
0040-4039(1995)36:38<6875:HOM2.N>2.0.ZU;2-V
Abstract
The heterocyclic berate complex obtained by hydroboration of methyl 2- acetamidoacrylate acts as an ambident nucleophile, affording N- or C-a lkyl or acylalaninates according to experimental conditions. Mechanist ic hypotheses are proposed to rationalize these results.