THE EFFECT OF SOLVENT ON THE ALPHA-EFFECT - ABNORMAL NUCLEOPHILIC REACTIVITY OF SUBSTITUTED ACETOPHENONE OXIMATE ANIONS IN AQUEOUS DMSO

Authors
UM IH OH SJ KWON DS
Citation
Ih. Um et al., THE EFFECT OF SOLVENT ON THE ALPHA-EFFECT - ABNORMAL NUCLEOPHILIC REACTIVITY OF SUBSTITUTED ACETOPHENONE OXIMATE ANIONS IN AQUEOUS DMSO, Tetrahedron letters, 36(38), 1995, pp. 6903-6906
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
38
Year of publication
1995
Pages
6903 - 6906
Database
ISI
SICI code
0040-4039(1995)36:38<6903:TEOSOT>2.0.ZU;2-M
Abstract
The nucleophilic reactivity of substituted acetophenone oximate anions decreases with increasing base strengthening ability of the substitue nt, resulting in a positive Hammett rho value in H2O containing 20 mol e% DMSO.