EFFECT OF MEDIUM ON THE RATE-CONSTANT OF DECOMPOSITION OF DI(TERT-BUTYL)TRIOXIDE

Authors
KHALIZOV AF KHURSAN SL SHERESHOVETS VV
Citation
Af. Khalizov et al., EFFECT OF MEDIUM ON THE RATE-CONSTANT OF DECOMPOSITION OF DI(TERT-BUTYL)TRIOXIDE, Russian chemical bulletin, 44(6), 1995, pp. 1127-1128
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
6
Year of publication
1995
Pages
1127 - 1128
Database
ISI
SICI code
1066-5285(1995)44:6<1127:EOMOTR>2.0.ZU;2-O
Abstract
It was found that the medium affects the rate constant of the thermal decomposition of di(tert-butyl)trioxide. In all solvents studied, the decomposition occurred according to the first-order law. The effect of the solvent on the rate constant was analyzed within the framework of the Koppel-Palm equation.