GAS SEPARATION PROPERTIES OF AROMATIC POLYAMIDES CONTAINING HEXAFLUOROISOPROPYLIDENE GROUPS

The synthesis and gas transport properties of aromatic polyisophthalam ides (PIPAs), based on isophthaloyl chloride derivatives bearing pende nt groups and hexafluoroisapropylidene (6F) linkages in the main chain , are reported and compared with properties of a similar series of PIP As containing sulfonyl (SO2) rather than 6F in the main chain. All of these polymers exhibit high glass transitions temperatures. The polyme rs containing 6F groups were markedly more permeable and somewhat less selective than their sulfonyl analogs. Polymers containing a t-butyl pendent group at the 5 position of the isophthaloyl linkage were much more permeable than those bearing only a hydrogen atom at this positio n, although a strong decrease in permselectivity accompanied the large increase in permeability. CO2/CH4 solubility selectivity values of th e BF-containing polymers were similar to values reported for other pol ymeric and non-polymeric organic materials with similar concentrations of polar carbonyl linkages. In contrast, the CO2/CH4 solubility selec tivity in SO2-containing variants of these polymers was substantially lower than expected based on total polar group concentration. The low CO2/CH4 solubility selectivity is believed to be related to the extrem ely efficient chain packing in the SO2-containing polymers, which may lead to strong amide-amide linkage interaction, thereby inhibiting car bonyl groups in the amide linkage from interactions with CO2 molecules to increase CO2/CH4 solubility selectivity.