DOPPLER-LIMITED SPECTROSCOPY AT CRYOGENIC TEMPERATURES - APPLICATION OF COLLISIONAL COOLING

A coolable gas cell for the measurement of mid-infrared spectra of gas es at cryogenic temperatures as low as 77 K is described. The design o f the cell allows it to be operated in collisional cooling (or diffusi ve trapping) mode to generate significant nonequilibrium pressures of monomer vapor for gases which would normally have vanishingly small va por pressure at low temperatures. Fourier transform infrared spectra o f carbon dioxide (CO2), nitrogen dioxide (NO2), and methyl silane (CH3 SiH3) vapors cooled by collisions with helium gas at 77 K are reported . Sufficiently high concentrations of monomer gas may be produced at l ow total pressure conditions (<10 hPa) to allow spectra to be recorded at the Doppler resolution limit. The resulting spectroscopic simplifi cation indicates that efficient collisional cooling of the vibrational , as well as rotational, degrees of freedom occurs. (C) 1995 American Institute of Physics.