D. Leythaeuser et al., PRESSURE SOLUTION IN CARBONATE SOURCE ROCKS AND ITS CONTROL ON PETROLEUM GENERATION AND MIGRATION, Marine and petroleum geology, 12(7), 1995, pp. 717-733
Based on detailed geochemical and petrographic studies of conventional
cores of a Triassic age carbonate source rock formation from three we
ll sites at increasing maturity stages, it is shown that the effects o
f carbonate diagenesis, especially pressure solution during relatively
shallow burial stages, exercise major controls on the processes of pe
troleum generation and migration during deeper burial. Pressure soluti
on leads to an internal redistribution of organic matter within this s
ource rock formation in the form of local concentrations as solution s
eams and stylolites. They provide very favourable conditions for effec
tive petroleum generation and migration due to their internal structur
e and composition (three-dimensional arrangement of kerogen surrounded
by carbonate-cemented rims as tight seals). The geochemical and petro
graphic effects of petroleum generation and expulsion are documented,
e.g. the expulsion of petroleum occurred as a separate phase fluid, at
high efficiencies (60-80% for the normal and isoprenoid alkanes) and
was facilitated by fractures presumably resulting from pore fluid over
pressuring. A five-stage conceptual model is proposed to explain how t
he effects of pressure solution achieved during relatively shallow bur
ial stages exercised controls on the extent and efficiency of petroleu
m generation and expulsion during deeper burial stages.