SYNTHESIS OF TETRAAMINOALKENES CONTAINING THE REDUCED PYRIMIDINE SKELETON AND THE X-RAY MOLECULAR-STRUCTURE OF LENE-3,3'-DIBENZYLBI(HEXAHYDROPYRIMIDIN-2-YLIDENE)
B. Alici et al., SYNTHESIS OF TETRAAMINOALKENES CONTAINING THE REDUCED PYRIMIDINE SKELETON AND THE X-RAY MOLECULAR-STRUCTURE OF LENE-3,3'-DIBENZYLBI(HEXAHYDROPYRIMIDIN-2-YLIDENE), Journal of chemical research. Synopses, (12), 1996, pp. 516-517
Deprotonation of a 1,1'-bridged bis(1,3-diaikyl-1,4,5,6-tetrahydropyri
midinium) diiodide with NaH gives in high yield a tetraaminoalkene 4,
whereas the corresponding non-bridged tetrahydropyrimidinium iodide re
acts with NaH only in the presence of KOBu; the title bridged tetraami
noalkene 4f was structurally characterized by single-crystal X-ray dif
fraction.