TANDEM ARYNE SEQUENCE ROUTE TO THE SYNTHESIS OF SUBSTITUTED FLUORENONES

Citation
P. Rajakumar et V. Murali, TANDEM ARYNE SEQUENCE ROUTE TO THE SYNTHESIS OF SUBSTITUTED FLUORENONES, Synthetic communications, 25(22), 1995, pp. 3537-3544
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
25
Issue
22
Year of publication
1995
Pages
3537 - 3544
Database
ISI
SICI code
0039-7911(1995)25:22<3537:TASRTT>2.0.ZU;2-L
Abstract
Substituted m-terphenyl carboxylic acids of the type 1a-e were prepare d by the tandem aryne sequence from substituted dihaloiodobenzenes wit h arylmagnesium bromide followed by quenching with CO2. The carboxylic acids la-e were converted into fluorenones 2a-e using either H2SO4 in CH3OH or PPA.