ELECTROCHEMICAL ACTIVATION OF MAGNESIUM - A NEW, RAPID AND EFFICIENT METHOD FOR THE ELECTROSYNTHESIS OF 1,1-DICHLOROALKYLPHOSPHONATES FROM DIISOPROPYL TRICHLOROMETHYLPHOSPHONATE

Authors
JUBAULT P FEASSON C COLLIGNON N
Citation
P. Jubault et al., ELECTROCHEMICAL ACTIVATION OF MAGNESIUM - A NEW, RAPID AND EFFICIENT METHOD FOR THE ELECTROSYNTHESIS OF 1,1-DICHLOROALKYLPHOSPHONATES FROM DIISOPROPYL TRICHLOROMETHYLPHOSPHONATE, Tetrahedron letters, 36(39), 1995, pp. 7073-7076
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
39
Year of publication
1995
Pages
7073 - 7076
Database
ISI
SICI code
0040-4039(1995)36:39<7073:EAOM-A>2.0.ZU;2-K
Abstract
Various diisopropyl 1,1-dichloroalkylphosphonates were easily and rapi dly prepared under mild conditions, by electrolysing, in DMF medium, d iisopropyl trichloromethylphosphonate in the presence of alkylating re agents. The use of an electrochemical activated magnesium anode signif icantly improved the rate and the yield of the reaction.