Self-trapping of holes at specific weak Si-Si bonds in a-Si:H is consi
dered on the basis of an extrinsic mechanism of self-trapping suggeste
d by experimental evidence. The nature of the hole wave function is el
ucidated from a tight-binding approach on the basis of optically detec
ted electron-nuclear double resonance experiments. Phenomena related t
o self-trapping of holes and excitons are discussed.