We have built a particle analyzer capable of real-time detection and c
haracterization of individual particles. Particle analysis is accompli
shed by pulsed laser ablation of a particle followed by time-of-flight
mass spectrometry of the resulting atomic and molecular ions. The det
ected ions are characteristic of a particle's molecular composition. P
articles of different sizes (0.02-10 mu m) and compositions (ammonium
sulfate, silica, rubidium nitrate, and cesium nitrate) have been detec
ted and characterized. Even refractory materials, e.g. silica, are eas
ily detected.