The transition line between tetragonal and rhombohedral phases in PZT
ceramics has been studied on the basis of X-ray diffraction data, with
a view to establishing the morphotropic phase boundary (MPB). In cera
mic manufacturing technology, piezoelectric PZT ceramic compositions a
re most likely to be near the morphotropic phase boundary. This bounda
ry can move when even small levels of dopants are present in the PZT c
eramics.