THERMOCHEMICAL AND ELECTROCHEMICAL STUDY OF SODIUM AND ZINC INSERTIONINTO ALPHA-UO3-Y AND ALPHA-U3O8

Citation
Re. Dueber et al., THERMOCHEMICAL AND ELECTROCHEMICAL STUDY OF SODIUM AND ZINC INSERTIONINTO ALPHA-UO3-Y AND ALPHA-U3O8, Solid state ionics, 80(3-4), 1995, pp. 231-238
Citations number
19
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
ISSN journal
01672738
Volume
80
Issue
3-4
Year of publication
1995
Pages
231 - 238
Database
ISI
SICI code
0167-2738(1995)80:3-4<231:TAESOS>2.0.ZU;2-I
Abstract
New sodium and zinc insertion compounds of the uranium oxides UO2.95(a lpha-UO3) and UO2.67(alpha-U3O8), were synthesized at ambient temperat ure. Enthalpies of formation were measured calorimetrically and corres ponding free energies of formation were determined electrochemically. Electronic changes on insertion were monitored by measurements of magn etic susceptibilities.