ASYMMETRIC HETERO-DIELS-ALDER REACTION CATALYZED BY CHIRAL YTTERBIUM(III) PHOSPHATE (YB[(R)-(-)-BNP](3)) - REMARKABLE LIGAND EFFECT ON THE ENANTIOSELECTIVITY

Authors
HANAMOTO T FURUNO H SUGIMOTO Y INANAGA J
Citation
T. Hanamoto et al., ASYMMETRIC HETERO-DIELS-ALDER REACTION CATALYZED BY CHIRAL YTTERBIUM(III) PHOSPHATE (YB[(R)-(-)-BNP](3)) - REMARKABLE LIGAND EFFECT ON THE ENANTIOSELECTIVITY, Synlett, (1), 1997, pp. 79
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
1
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):1<79:AHRCBC>2.0.ZU;2-O
Abstract
2,6-Lutidine was found to be an effective additive for the chiral ytte rbium(III) phosphate {Yb[(R)-(-)-BNP](3)}-catalyzed asymmetric hetero Diels-Alder reaction thus achieving high enantioselectivity (up to 93% ee) at room temperature.