MINERALOGICAL SITING AND DISTRIBUTION OF GOLD IN QUARTZ VEINS AND SULFIDE ORES OF THE ASHANTI MINE AND OTHER DEPOSITS IN THE ASHANTI BELT OF GHANA - GENETIC-IMPLICATIONS

The Ashanti belt of Ghana constitutes a gold province which has produc ed a total of about 1500 t of gold historically. Gold mineralization i s found in steep, NNE-SSW to NE-SW trending shear zones predominantly transecting metasediments of the Palaeoproterozoic Birimian Supergroup (2.2-2.1 Ga), disseminated in ca. 2.1 Ga granitoids, in paleo-conglom erates of the Tarkwaian Group (< 2135 Ma), and in recent placers. The distribution of gold, its chemistry, paragenesis and mineralogical sit ing in the mesothermal ores of the major mines in the Ashanti belt, na mely Konongo, Ashanti, Bogosu and Prestea mine, are the subject of thi s study. At the localities studied, gold is present in two main types of ores: 1. Quartz veins with free-milling gold. The gold is relativel y silver-rich (true fineness values from 730 to 954) and is accompanie d by a distinct suite of Cu, Pb, Sb sulfides. 2. Sulfide ores, consist ing of arsenopyrite, pyrite and rarer pyrrhotite and marcasite, with r efractory gold. The ores have apparent fineness values larger than 910 . Arsenopyrite and locally (at Bogosu) pyrite were identified as the h osts of submicroscopic gold. Mean concentrations of gold in arsenopyri te in various samples from the different mines, obtained by secondary ion mass spectrometry (SIMS), range from 67 to 314 ppm Au. Gold concen tration mapping in individual arsenopyrite crystals from the different deposits revealed similar patterns of gold distribution: the grains p ossess a gold-poor core, and elevated gold contents are present along distinct crystal growth zones towards their rims. The outermost crysta l layer is usually gold-poor. The well-preserved distribution patterns also indicate that remobilization of gold from the sulfides played an insignificant role in the ores of the Ashanti belt. Multiple quartz v eining and growth zoning of the sulfides are interpreted as manifestat ions of multiple episodes of fluid in filtration, fluid flow and miner al deposition. The bimodal occurrence of gold in spatially closely ass ociated quartz vein and sulfide ores indicates a genetic link between these ore types. A model implying a grossly coeval formation of the or es from mesothermal fluids is proposed.