KINETICS AND PRODUCTS OF THE GAS-PHASE REACTIONS OF (CH3)(4)SI, (CH3)(3)SICH2OH, (CH3)(3)SIOSI(CH3)(3) AND (CD3)(3)SIOSI(CD3)(3) WITH CL ATOMS AND OH RADICALS
R. Atkinson et al., KINETICS AND PRODUCTS OF THE GAS-PHASE REACTIONS OF (CH3)(4)SI, (CH3)(3)SICH2OH, (CH3)(3)SIOSI(CH3)(3) AND (CD3)(3)SIOSI(CD3)(3) WITH CL ATOMS AND OH RADICALS, Journal of the Chemical Society. Faraday transactions, 91(18), 1995, pp. 3033-3039
Citations number
24
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Direct air-sampling atmospheric-pressure ionisation tandem mass spectr
ometry and FTIR spectroscopy were used to analyse the products of the
OH radical- and Cl atom-initiated reactions of hexamethyldisiloxane, [
H-2(18)]hexamethyldisiloxane, tetramethylsilane and trimethylsilylmeth
anol at room temperature and atmospheric pressure. The data obtained i
ndicate the initial formation of (CH3)(3)SiOSi(CH3)(2)OCHO and (CD3)(3
)SiOSi(CD3)(2)OCDO from hexamethyldisiloxane and [H-2(18)]hexamethyldi
siloxane, respectively, and (CH3)(3)SIOCHO from both tetramethylsilane
and trimethylsilylmethanol.