STUDIES ON TRANSITION-METAL PARACYCLOPHANE COMPOUNDS - REACTIONS OF [(M(ETA(6)-C16H16)CL-2)(2)] (M=RU, OS) WITH TERTIARY PHOSPHINES - THE CRYSTAL-STRUCTURES OF [RU(ETA(6)-C16H16)CL-2(PPH(3))].CHCL3 AND [RU(ETA(6)-C6H6)CL-2(PPH(3))].2CH(2)CL(2)

Authors
ELSEGOOD MRJ TOCHER DA
Citation
Mrj. Elsegood et Da. Tocher, STUDIES ON TRANSITION-METAL PARACYCLOPHANE COMPOUNDS - REACTIONS OF [(M(ETA(6)-C16H16)CL-2)(2)] (M=RU, OS) WITH TERTIARY PHOSPHINES - THE CRYSTAL-STRUCTURES OF [RU(ETA(6)-C16H16)CL-2(PPH(3))].CHCL3 AND [RU(ETA(6)-C6H6)CL-2(PPH(3))].2CH(2)CL(2), Polyhedron, 14(20-21), 1995, pp. 3147-3156
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
20-21
Year of publication
1995
Pages
3147 - 3156
Database
ISI
SICI code
0277-5387(1995)14:20-21<3147:SOTPC->2.0.ZU;2-G
Abstract
The synthesis of the compound [{Os(eta(6)-C16H16)Cl-2}(2)] is describe d. The reactions of the compounds [{M(eta(6)-C16H16)Cl-2}(2)] (M = Ru, Os) with tertiary phosphines are investigated inpolar and non-polar s olvents. Neutral compounds [M(eta(6)-C16H16)Cl-2(PR(3))] and cationic complexes [M(eta(6)-C16H16)Cl(PR(3))(2)](+)X(-) (X = PF6, BPh(4)) are obtained, respectively. The crystal structure of a representative comp ound [Ru(eta(6)-C16H16)Cl-2(PPh(3))] has been determined and the struc ture is compared with that of the simpler analogue [Ru(eta(6)-C6H6)Cl- 2(PPh(3))].