METAL-DIRECTED SELF-ASSEMBLY OF REDOX-ACTIVE BIMETALLOMACROCYCLES CONTAINING 6-COORDINATE METAL CENTERS INCORPORATED INTO 16-MEMBERED, 18-MEMBERED AND 24-MEMBERED RINGS

Authors
MCQUILLAN FS JONES CJ MCCLEVERTY JA
Citation
Fs. Mcquillan et al., METAL-DIRECTED SELF-ASSEMBLY OF REDOX-ACTIVE BIMETALLOMACROCYCLES CONTAINING 6-COORDINATE METAL CENTERS INCORPORATED INTO 16-MEMBERED, 18-MEMBERED AND 24-MEMBERED RINGS, Polyhedron, 14(20-21), 1995, pp. 3157-3161
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
20-21
Year of publication
1995
Pages
3157 - 3161
Database
ISI
SICI code
0277-5387(1995)14:20-21<3157:MSORBC>2.0.ZU;2-5
Abstract
The reaction between [Mo(NO)Tpl(2)] [Tp* = HB(3,5-Me(2)C(3)HN(2))(3)] and the bifunctional ligands BLH(2) (BL = 4,4'-OC6H4CH2C6H4O, 4,4'-OC H2C6H4CH2O and 2,7-O2C10H6) in the presence of NEt(3) affords the redo x active metallomacrocycles [Mo(NO) Tp(BL)](2) which have been isolat ed as syn- and anti-isomers, except where BL = 4,4'-OCH2C6H4CH2O, and characterized by spectroscopic and electrochemical methods.