I. Panaiotov et al., SPREADING KINETICS OF DIMYRISTOYLPHOSPHATIDYLCHOLINE LIPOSOMES AT THEAIR WATER INTERFACE BELOW AND ABOVE THE MAIN PHASE-TRANSITION TEMPERATURE/, Colloids and surfaces. A, Physicochemical and engineering aspects, 102, 1995, pp. 159-165
The spreading kinetics of dimyristoylphosphatidylcholine liposomes at
the air/water interface, below and above the main phase-transition tem
perature are studied by measuring the evolution of the surface pressur
e. The reorganization mechanism of the closed liposomal bilayers into
a surface film is dependent on the state of the bilayer. The estimated
values of the interfacial reorganization rate constant for liposomes
in a liquid-crystal state are larger than those for liposomes in cryst
al-gel state. Atomic force microscopic imaging demonstrates the differ
ent morphology of the interfacial mesophases obtained.