SYNTHESIS AND POLYMERIZATION OF -METHYL(VINYLBENZYL)TETRACHLOROCYCLOTRIPHOSPHAZENE

Authors
BOSSCHER G VANDEGRAMPEL JC
Citation
G. Bosscher et Jc. Vandegrampel, SYNTHESIS AND POLYMERIZATION OF -METHYL(VINYLBENZYL)TETRACHLOROCYCLOTRIPHOSPHAZENE, Journal of inorganic and organometallic polymers, 5(3), 1995, pp. 209-216
Citations number
16
Categorie Soggetti
Polymer Sciences
Journal title
Journal of inorganic and organometallic polymers → ACNP
ISSN journal
10530495
Volume
5
Issue
3
Year of publication
1995
Pages
209 - 216
Database
ISI
SICI code
1053-0495(1995)5:3<209:SAPO->2.0.ZU;2-5
Abstract
A new styrene-substituted chlorocyclotriphosphazene, gem-methyl(vinylb enzyl) tetrachlorocyclotriphosphazene, has been prepared from vinylben zylmagnesium chloride and hexachlorocyclotriphosphazene. The organosub stituted chlorocyclotriphosphazene has been used in radical homo- and copolymerization with methyl methacrylate. The reactivity ratios for t he MMA copolymerization show a small effect of the phosphazene ring on the olefin reactivity. All these polymers exhibit flame-retardant pro perties.