THE GRAPHICAL SPIN ALGEBRA METHOD APPLIED TO U(2N) GENERATORS

Authors
Citation
Mw. Lucht et Md. Gould, THE GRAPHICAL SPIN ALGEBRA METHOD APPLIED TO U(2N) GENERATORS, The Journal of chemical physics, 103(13), 1995, pp. 5590-5599
Citations number
26
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
103
Issue
13
Year of publication
1995
Pages
5590 - 5599
Database
ISI
SICI code
0021-9606(1995)103:13<5590:TGSAMA>2.0.ZU;2-H
Abstract
An efficient method for the evaluation of the matrix elements of U(2n) spin-dependent generators in a fully spin adapted Gelfand-Tsetlin bas is is given. This is done by evaluating the matric elements of the U(2 n) generators in a Yamanouchi-Kotani basis whose orbital part is equiv alent, up to phase factors, to the Gelfand-Tsetlin basis. This allows the expression for the matrix elements to be separated into products o f creation and annihilation operators, which are evaluated using Wick' s theorem, and products of SU(2) Clebsch-Gordan coefficients, whose sp in graphs are factorized into easily evaluated segment diagrams. The m atrix elements of a single U(2n) generator reduce to a sum of products of segment values. These values are given in formula form involving 3 -j and 6-j symbols and in table form, where the formulas have been eva luated for all the nonvanishing segments. (C) 1995 American Institute of Physics.