ORGANOPHOSPHORIC COMPOUNDS WITH BETA-CYAN OETHYL-TYPE STRUCTURAL ELEMENTS .1. SYNTHESIS OF BETA-CYANOETHYLATED PHOSPHONO-AMIDE AND PHOSPHORO-AMIDE

The paper presents three types of phosphorylation reactions for the 3, 3'-imino-di-propionitrile mixture with N,N,N-tris-(beta-cyanoethyll) a mine, as results from the reaction of ammonia nucleophilic addition to acrylonitrile. The reaction of amines mixture phosphorylation with di alkyl phosphite by interphase transfer catalysis leads to compounds of the diester-phosphoromonoamide beta-cyanoethylate class formation. Th e phosphono-and phosphorotriamide hexa beta-cyanoethylates are obtaine d by the amine mixture reaction with the phosphorous trichloride and o xichloride respectively.