SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF 2 ETA(1)-BONDED N-PHENYLTHIOFORMAMIDATE COMPLEXES OF RHODIUM

Authors
MCENEANEY PA SPALDING TR FERGUSON G
Citation
Pa. Mceneaney et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF 2 ETA(1)-BONDED N-PHENYLTHIOFORMAMIDATE COMPLEXES OF RHODIUM, Journal of the Chemical Society. Dalton transactions, (2), 1997, pp. 145-147
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
2
Year of publication
1997
Pages
145 - 147
Database
ISI
SICI code
0300-9246(1997):2<145:SASCO2>2.0.ZU;2-1
Abstract
The complexes SC(H)NPh}-3,3-(PMe(2)Ph)(2)-3,1,2-closo-RhC2B9H11] and - SC(H)NPh}-2,2-(PMe(2)Ph)(2)-2,1-closo-RhTeB10H10] have been structural ly characterised using X-ray crystallography and are the first eta(1)- bonded thioformamidate complexes to be isolated.