HETEROLEPTIC METALLACYCLIC POTASSIUM ORGANODIAMIDO ZINCATE COMPLEX - SYNTHESIS AND STRUCTURE OF POLYMERIC ([K(THF)][MEZN(BU(T)NCH=CHNBU(T))])(N)

Authors
RIJNBERG E BOERSMA J JASTRZEBSKI JTBH LAKIN MT SPEK AL VANKOTEN G
Citation
E. Rijnberg et al., HETEROLEPTIC METALLACYCLIC POTASSIUM ORGANODIAMIDO ZINCATE COMPLEX - SYNTHESIS AND STRUCTURE OF POLYMERIC ([K(THF)][MEZN(BU(T)NCH=CHNBU(T))])(N), Journal of the Chemical Society, Chemical Communications, (18), 1995, pp. 1839-1840
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
18
Year of publication
1995
Pages
1839 - 1840
Database
ISI
SICI code
0022-4936(1995):18<1839:HMPOZC>2.0.ZU;2-W
Abstract
The reaction of the C-C coupled dimer oi two neutral organozinc radica ls, [MeZn{Bu(t)N=CHCH(NBu(t))CH(NBu(t))CH=NBu(t)}ZnM] 1, with potassiu m in tetrahydrofuran affords the metallacyclic heteroleptic potassium organodiamido zincate K[MeZn(Bu(t)NCH=CHNBu(t))] 2 quantitatively, whi ch exists in the solid state (X-ray crystallography) as a linear polym er formed by alternating Potassium cations and organodiamidozincate an ions.