THEORETICAL APPROACH AND FIRST EXAMPLES OF N-ACYL-THIOFORMAMIDES AS DIENOPHILES IN THE DIELS-ALDER REACTION

Authors
ARNAUD R CHAVANT PY MOLVINGER K VALLEE Y
Citation
R. Arnaud et al., THEORETICAL APPROACH AND FIRST EXAMPLES OF N-ACYL-THIOFORMAMIDES AS DIENOPHILES IN THE DIELS-ALDER REACTION, Journal of the Chemical Society, Chemical Communications, (18), 1995, pp. 1897-1898
Citations number
27
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
18
Year of publication
1995
Pages
1897 - 1898
Database
ISI
SICI code
0022-4936(1995):18<1897:TAAFEO>2.0.ZU;2-U
Abstract
ab initio Calculations as well as experimental results show that the C = S bond of a thioamide can act as a dienophile in the Diels-Alder re action provided that the nitrogen atom is substituted by pi-acceptor g roups.