Ss. Tandon et al., A NOVEL TETRANUCLEAR COPPER(II) COMPLEX WITH 3 DIFFERENT TYPES OF AZIDE, EXHIBITING WEAK ANTIFERROMAGNETIC EXCHANGE, Journal of the Chemical Society, Chemical Communications, (18), 1995, pp. 1907-1908
The antiferromagnetically coupled, tetranuclear copper(II) complex u-1
,1-N-3)(2)(mu-1,1-N-3)(2)(mu-MeOH)(2)(N-3)(4)]1 contains a unique stru
ctural arrangement with two mu-1,1-azide intramolecular bridges, and t
wo mu-1,3-azide intermolecular bridges linking pairs of copper(II) cen
tres, in addition to four terminal azide groups.