Wg. Fisher et al., NONDESTRUCTIVE INSPECTION OF GRAPHITE-EPOXY COMPOSITES FOR HEAT DAMAGE USING LASER-INDUCED FLUORESCENCE, Applied spectroscopy, 49(9), 1995, pp. 1225-1231
Laser-induced fluorescence has been applied to the nondestructive insp
ection of graphite-fiber-reinforced polymer-matrix composites. Upon cu
ring, the epoxy resin in these materials forms a highly cross-linked n
etwork of aromatic sub-units. This result yields a material with signi
ficant absorptivity from the ultraviolet through the near-infrared and
a fluorescence bandwidth covering 200 to 300 nm. When subjected to te
mperatures beyond the recommended upper service temperature, these mat
erials experience thermally induced degradation and a reduction in mec
hanical strength. Furthermore, these heat-damaged materials exhibit si
gnificant changes in fluorescence intensity and in the wavelength of m
aximum fluorescence intensity. These spectroscopic changes can be corr
elated with the extent of heat damage. An imaging approach has been de
veloped to monitor these fluorescence signatures, allowing rapid nonde
structive inspection of large surface areas. This capability provides
qualitative and quantitative information about the location and severi
ty of damage.