ENYLPHOSPHINE-CLOSO-1,2-SELENACUPRADODECABORANE(8)

Authors
THORNTONPETT M KENNEDY JD BREEN SP SPALDING TR
Citation
M. Thorntonpett et al., ENYLPHOSPHINE-CLOSO-1,2-SELENACUPRADODECABORANE(8), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1496-1498
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
8
Pages
1496 - 1498
Database
ISI
SICI code
0108-2701(1995)51:<1496:E>2.0.ZU;2-5
Abstract
The title compound, 11-mu(3)-[(mu-H)(2)CU(PPh(3))]2-(PPh(3))-closo-2,1 -CuSeB10H8}, [CU2(C18H15P)-(C18H25B10PSe)], has an icosahedral closo- CuSeB10 cage with Cu and Se atoms adjacent [Se1-Cu2 2.3939(6)Angstrom] . An exo-cage [Cu(PPh(3))]-unit is bonded to one triangular CuB2 face via a Cu-Cu bond [Cu-2-Cu3 2.6470(7)Angstrom] and two B-H-Cu3 interact ions [Cu3-H7 1.97(3), Cu3-H11 1.86(2), Cu3 ... B72.234(3), Cu3 ... B11 2.158(3)Angstrom].