3-(TERT-BUTYL TAHYDRO-1,2-DIARSA-3-PALLADA-CLOSO-DODECABORON(1+) HEXAFLUOROANTIMONATE

Authors
FERGUSON G LI YW SPALDING TR PATTERSON JC
Citation
G. Ferguson et al., 3-(TERT-BUTYL TAHYDRO-1,2-DIARSA-3-PALLADA-CLOSO-DODECABORON(1+) HEXAFLUOROANTIMONATE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1498-1500
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
8
Pages
1498 - 1500
Database
ISI
SICI code
0108-2701(1995)51:<1498:3TH>2.0.ZU;2-Q
Abstract
The title compound, [Pd(C5H9N)(C8H11P){B9H8As2- (C8H11P)}][SbF6], cont ains a twelve-vertex (PdAs2B9) cage with the metal eta(5)-bonded to an AS(2)B(3) ring. The exo-cage ligands dimethylphenylphosphine and tert butyl isocyanide are attached to Pd and a second PMe(2)Ph ligand is at tached to a cage B atom at position 8. The Pd-As interactions are nota bly asymmetric at 2.6434(8) and 2.5296(7)Angstrom. Other principal dim ensions are Pd-B 2.291(6)-2.301, Pd-P 2.330(2), Pd-C 2.011(6) and As-A s 2.492(1) Angstrom.