TETRAKIS(MU-DL-ALANINE-O-O')OCTA-AGUADIERBIUM(III) HEXAPERCHLORATE

Citation
Nh. Hu et al., TETRAKIS(MU-DL-ALANINE-O-O')OCTA-AGUADIERBIUM(III) HEXAPERCHLORATE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1565-1568
Citations number
13
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
8
Pages
1565 - 1568
Database
ISI
SICI code
0108-2701(1995)51:<1565:TH>2.0.ZU;2-S
Abstract
The structure of the title compound, [Er-2(C3H7NO2)(4)- (H2O)(8)](ClO4 )(6), consists of dimeric [Er-2(DL-alanine)(4)-(H2O)(8)](6+) cations a nd perchlorate anions. The four alanine molecules act as bridging liga nds linking two Er3+ ions through their carboxyl O atoms. Each Er3+ io n is also coordinated by four water molecules to complete eightfold co ordination in a square antiprism fashion. The perchlorate anions and t he methyl groups of the alanine ligands are disordered.