4,5-BIS(2,4-DINITROPHENYLTHIO)-1,3-DITHIOL-2-ONE NITROMETHANE SOLVATE(BNPT-DTO.CH3NO2)

Authors
YU WT QI F DONG X JIANG MH HONG L
Citation
Wt. Yu et al., 4,5-BIS(2,4-DINITROPHENYLTHIO)-1,3-DITHIOL-2-ONE NITROMETHANE SOLVATE(BNPT-DTO.CH3NO2), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 1602-1604
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
8
Pages
1602 - 1604
Database
ISI
SICI code
0108-2701(1995)51:<1602:4NS>2.0.ZU;2-H
Abstract
The unit cell of the title crystal, C15H6N4O9S4.CH3NO2, contains two B NPT-DTO molecules and two co-crystallized nitromethane solvent molecul es. A BNPT-DTO molecule comprises one conjugated 4,5-dimercapto-1,3-di thiol-2-one plane (analogous to 4,5-dimercapto-1,3-dithiole-2-thione, DMIT) and two phenyl planes which are almost perpendicular to the 'DMI T' plane. The dihedral angle between the phenyl planes is 45.8 degrees . The crystal packing is stabilized by a number of intermolecular inte ractions in addition to normal van der Waals interactions.