AsPh(2)I (iododiphenylarsine) contains arsenic in trigonal pyramidal c
oordination with iodine and two phenyl groups, with effectively equal
As-C distances [1.953 (6) and 1.942 (6) Angstrom]. Bond angles at arse
nic are 101.7(2)degrees between the phenyl groups and a mean of 97.5 d
egrees between iodine and phenyl. There are no intermolecular As ... I
interactions shorter than 4.4 Angstrom.