The on-momentum description of linear coupling between horizontal and
vertical betatron motion is extended to include off-momentum particles
, introducing a vector quantity called the ''skew chromaticity''. This
vector tends to be long in large superconducting storage rings, where
it restricts the available working space in the tune plane, and modif
ies collective effect stability criteria. Skew chromaticity measuremen
ts at the Cornell Electron Storage Ring (CESR) and at the Fermilab Tev
atron are reported, as well as tracking results from the Relativistic
Heavy ion Collider (RHIC). The observation of anomalous head-tail beam
losses near the tune diagonal in the Tevatron are explained in terms
of the extended theory, including modified criteria for head-tail stab
ility. These results are confirmed in head-tail simulations. Sources o
f skew chromaticity are investigated.