Silicalite-alumina composite membranes were prepared by an in situ zeo
lite synthesis method using an alumina membrane tube with a 5-nm pore
diameter, gamma-alumina layer as a substrate. Single gas permeances of
H-2, Ar, n-C4H10, i-C4H10, and SF6 were measured and mixtures of H-2/
i-C4H10 and H-2/SF6 were separated to characterize the silicalite memb
rane. These measurements were made from 300 to 737 K, and are compared
to an alumina membrane without a silicalite layer. Permeances were lo
wer in the silicalite membrane (a factor of 8 for Ar at 298 K). Permea
nces for the alumina membrane decreased as the temperature increased,
and separation selectivities were lower than values expected for Knuds
en diffusion. Transport through the alumina membrane was by Knudsen fl
ow and surface diffusion. The silicalite membrane showed dramatically
different behavior, and transport appeared to be controlled by molecul
ar size and adsorption properties. Permeances of all components studie
d were activated in the silicalite membrane, and activation energies r
anged from 8.5 to 16.2 kJ/mol. The ratio of single gas permeances was
as high as 136 for H-2 to SF6 and 1100 for H-2 to i-C4H10 at 298 K. Se
paration selectivities at elevated temperatures were significantly abo
ve Knudsen diffusion selectivity for the silicalite membrane and were
larger than ratios of pure gas permeances at the same temperature. The
largest permeance ratio for the separation of mixtures was 12.8 for H
-2/SF6 at 583 K. Separation selectivities for both membranes were high
er when a pressure drop was maintained across the membrane than when a
n inert sweep gas was used because of counter diffusion of the sweep g
as.