HETEROGENEOUS CATALYSIS ON A DISORDERED SURFACE

Citation
L. Frachebourg et al., HETEROGENEOUS CATALYSIS ON A DISORDERED SURFACE, Physical review letters, 75(15), 1995, pp. 2891-2894
Citations number
19
Categorie Soggetti
Physics
Journal title
ISSN journal
00319007
Volume
75
Issue
15
Year of publication
1995
Pages
2891 - 2894
Database
ISI
SICI code
0031-9007(1995)75:15<2891:HCOADS>2.0.ZU;2-G
Abstract
We introduce a simple model of heterogeneous catalysis on a disordered surface which consists of two types of randomly distributed sites wit h different adsorption rates. Disorder can create a reactive steady st ate in situations where the same model on a homogeneous surface exhibi ts trivial kinetics with no steady state. A rich variety of kinetic be haviors occurs for the adsorbate concentrations and catalytic reaction rate as a function of model parameters.