The influence of the syndiotacticity on the crystallization behaviour
of syndiotactic polypropylene (sPP) has been investigated. The syndiot
acticity has been measured by C-13-NMR spectroscopy and the phase form
ation has been observed by electron diffraction of oriented samples. I
t is shown that the crystal phase formation depends strongly on the pe
rfection of the tacticity of the macromolecules.