THE REACTION OF CF3OOCF2OF WITH FLUOROOLEFINS

Authors
RUSSO A MONTANARI V NAVARRINI W DESMARTEAU DD
Citation
A. Russo et al., THE REACTION OF CF3OOCF2OF WITH FLUOROOLEFINS, Journal of fluorine chemistry, 74(1), 1995, pp. 83-87
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
74
Issue
1
Year of publication
1995
Pages
83 - 87
Database
ISI
SICI code
0022-1139(1995)74:1<83:TROCWF>2.0.ZU;2-E
Abstract
The reaction of fluoroxydifluoromethyl trifluoromethyl peroxide, CF3OO CF2OF (1), with fluoroolefins leads to the formation of novel fluorina ted peroxides as major products. When 1 was added to 1,2-dichloro-1,2- difluoroethylene, CFCl=CFCl, under controlled conditions,the formation of 4,5-dichloro-2,2,4,5-tetrafluoro-1,3-dioxolane was also observed. A mechanism is proposed to rationalize these results.