We have utilized atomic layer deposition to synthesize single crystal
thin films of cuprate superconductors, as well as a variety of superla
ttices and multilayer heterostructures with atomically abrupt interfac
es. For example, we made trilayer structures with the top and the bott
om BiSrCaCuO electrodes separated by titanate barriers that were only
4 Angstrom thick and yet free of pinholes over macroscopic areas. This
unique synthetic capability made it possible to study transport in th
e c-axis direction under controlled and systematically varied conditio
ns. Taken together, these experiments provide a picture of the c-axis
transport in 2201, 2212, and various heterostructures under study. In
particular, they suggest presence of a large density of localized stat
es near the Fermi level and thus support a two-component description o
f the electron system in these compounds.