SYNTHESES OF MONODISPERSED METHYL-METHACRYLATE OLIGOMERS VIA ORGANOLANTHANIDE COMPLEXES AND INTRODUCTION OF HYDROXYL-GROUPS INTO THE OLIGOMER

Authors
IHARA E TAGUCHI M YASUDA H
Citation
E. Ihara et al., SYNTHESES OF MONODISPERSED METHYL-METHACRYLATE OLIGOMERS VIA ORGANOLANTHANIDE COMPLEXES AND INTRODUCTION OF HYDROXYL-GROUPS INTO THE OLIGOMER, Applied organometallic chemistry, 9(5-6), 1995, pp. 427-429
Citations number
6
Categorie Soggetti
Chemistry Applied","Chemistry Inorganic & Nuclear
Journal title
Applied organometallic chemistry → ACNP
ISSN journal
02682605
Volume
9
Issue
5-6
Year of publication
1995
Pages
427 - 429
Database
ISI
SICI code
0268-2605(1995)9:5-6<427:SOMMOV>2.0.ZU;2-S
Abstract
Methyl methacrylate (MMA) oligomers (M(n) similar or equal to 2500) wi th a narrow molecular weight distribution (M(w)/M(n) < 1.10) were synt hesized by using a Cp(2)SmMe(THF) initiator (Co=eta-C). The oligomeri zation proceeds via a samarium enolate as the propagating species and the reaction of the living oligomer with p-tolualdehyde produced p-tol yl hydroxymethyl-terminated oligoMMA.